Self-Assemblies Based on [Cp2Mo2(CO)4(μ,η2-P2)]—Solid-State Structure and Dynamic Behaviour in Solution
✍ Scribed by Manfred Scheer; Laurence J. Gregoriades; Manfred Zabel; Junfeng Bai; Ingo Krossing; Gunther Brunklaus; Hellmut Eckert
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 511 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0947-6539
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📜 SIMILAR VOLUMES
## Abstract Reaction of the complex [{CpMo(CO)~2~}~2~(μ,η^2^‐P~2~)] (1) with Cu^I^ halides leads to the quantitative formation of the novel one‐dimensional linear polymers [CuX{Cp~2~Mo~2~(CO)~4~(μ,η^2^:η^1^:η^1^‐P~2~)}]~∞~ (X=Cl (4), Br (5), I (6)). The same products 4 and 5 were obtained when 1 wa
## Abstract Internal rotation about the C‐2–C‐3 bond was observed in the ^13^C CP‐MAS NMR spectra of the solid complexes [M~2~(ηHC^1^C^2^C^3^Me~2~)(CO)~4~(ηC~5~H~5~)~2~]^+^ [BF~4~]^−^ where M = Mo or W.