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Self-Assemblies Based on [Cp2Mo2(CO)4(μ,η2-P2)]—Solid-State Structure and Dynamic Behaviour in Solution

✍ Scribed by Manfred Scheer; Laurence J. Gregoriades; Manfred Zabel; Junfeng Bai; Ingo Krossing; Gunther Brunklaus; Hellmut Eckert


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
511 KB
Volume
14
Category
Article
ISSN
0947-6539

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## Abstract Reaction of the complex [{CpMo(CO)~2~}~2~(μ,η^2^‐P~2~)] (1) with Cu^I^ halides leads to the quantitative formation of the novel one‐dimensional linear polymers [CuX{Cp~2~Mo~2~(CO)~4~(μ,η^2^:η^1^:η^1^‐P~2~)}]~∞~ (X=Cl (4), Br (5), I (6)). The same products 4 and 5 were obtained when 1 wa

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## Abstract Internal rotation about the C‐2–C‐3 bond was observed in the ^13^C CP‐MAS NMR spectra of the solid complexes [M~2~(ηHC^1^C^2^C^3^Me~2~)(CO)~4~(ηC~5~H~5~)~2~]^+^ [BF~4~]^−^ where M = Mo or W.