Conformational Analysis of One-Dimensional Coordination Polymers Based on [Cp2Cr2(CO)4(μ,η2-P2)] by Solid-State Multinuclear NMR Spectroscopy and Density Functional Calculations

One-Dimensional Polymers Based on [{CpMo

One-Dimensional Polymers Based on [{CpMo(CO)2}2(μ,η2-P2)]: Solid-State Conformation Analysis by NMR Spectroscopy and DFT Calculations

✍ Manfred Scheer; Laurence Gregoriades; Junfeng Bai; Marek Sierka; Gunther Brunkla 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 211 KB

## Abstract Reaction of the complex [{CpMo(CO)~2~}~2~(μ,η^2^‐P~2~)] (1) with Cu^I^ halides leads to the quantitative formation of the novel one‐dimensional linear polymers [CuX{Cp~2~Mo~2~(CO)~4~(μ,η^2^:η^1^:η^1^‐P~2~)}]~∞~ (X=Cl (4), Br (5), I (6)). The same products 4 and 5 were obtained when 1 wa