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Selective transformation of N-t-butoxycarbonyl group into n-alkoxy-carbonyl group via n-carboxylate ion equivalent

โœ Scribed by Masahiro Sakaitani; Yasufumi Ohfune


Book ID
104233325
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
223 KB
Volume
26
Category
Article
ISSN
0040-4039

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Studies on the Transformation of Azido-Group to N-(t-Butoxycarbonyl)amino Group via Staudinger Reaction. -A simple and convenient method for the direct conversion of primary azides into N-Boc-amines [cf. (III), (V), (VII)] via iminophosphorane intermediates is described. The formation of symmetrica