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Selective synthesis of enanthic acid by the carbonylation of 1-hexene in the presence of palladium anion-exchange catalysts with SnCl2additive

✍ Scribed by A. L. Lapidus; S. D. Pirozhkov; M. A. Buiya; L. P. Karapetyan; K. M. Saldadze; R. A. Karakhanov


Book ID
112446238
Publisher
Springer
Year
1985
Tongue
English
Weight
77 KB
Volume
34
Category
Article
ISSN
1573-9171

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The regioselectivity of alkoxycarbonylation of 1-arylethanols catalysed by Pdracid systems is very sensitive to the nature of the counter anion of the acid: chloride anion favours branched products while tetrafluoroborate and sulfonates anions favour linear products, the latter ones enhancing also p