✦ LIBER ✦

Selective reduction of carbonyl compounds by diphenylstibine

✍ Scribed by Yaozeng Huang(Y.Z. Huang); Yanchang Shen; Chen Chen

Book ID: 104229046
Publisher: Elsevier Science
Year: 1985
Tongue: French
Weight: 110 KB
Volume: 26
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)98894-4

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✦ Synopsis

Numbers of metal hydrides and organometallic hydrides are able to reduce carbonyl compounds. Every hydrides has its own characteristic feature. However, no report is given in the literature concerning the r-activities of metal hydrides of main group V other than the addition of stibine with CsC and N=N bonds 2,3 . We found that in the absence of Lewis acids, diphenylstibine alone did not react with carbonyl compounds, but in the presence of Lewis acid, it did react at mild conditions to afford, after hydrolysis, alcohols in excellent yields.

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