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Reduction of carbonyl compounds by using polymethylhydro-siloxane: reactivity and selectivity

✍ Scribed by Yuichi Kobayashi; Eisuke Takahisa; Miwa Nakano; Kengo Watatani

Book ID: 104207460
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 542 KB
Volume: 53
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(96)01092-7

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✦ Synopsis

Reduction of aldehydes and ketones with PMHS [MqSiO-(SiMe(H)O),-SiMe31 proceeded smoothly in the presence of Bu4NF at -70 "C or 0 "C within 60 min in THF. High stereo-and chemoselectivities as well as functional group tolcrancc of this system are also presented.

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