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Selective oxidation of steroidal allylic alcohols using pyrazole and pyridinium chlorochoromate

✍ Scribed by Edward J. Parish; Sarawanee Chitrakorn; Susan Lowery

Book ID: 112772764
Publisher: Springer-Verlag
Year: 1984
Tongue: English
Weight: 174 KB
Volume: 19
Category: Article
ISSN: 0024-4201
DOI: 10.1007/bf02534489

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## Abstract A convenient and selective oxidation of alcohols with hydrogen peroxide to give aldehydes and ketones has been developed. Using __in situ__ generated iron chloride complexes [Fe(**L3**)~2~Cl~n~] [n=0–1, **L3** =6‐(__N__‐phenylbenzimidazoyl)‐2‐pyridinecarboxylic acid], aldehydes and keto