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Selective oxidation of steroidal allylic alcohols

โœ Scribed by E.J. Parish; G.J. Schroepfer Jr.


Book ID
107736960
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
397 KB
Volume
27
Category
Article
ISSN
0009-3084

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Further studies on the selective oxidati
โœ Edward J. Parish; Aubrey D. Scott; James R. Dickerson; Waite Dykes ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 264 KB

Certain aromatic amines, when used in conjunction with pyridinium chlorochromate, have been found to selectively oxidize the allylic hydroxyl group of steroidal alcohols to the corresponding a,/~-unsaturated ketones. In this respect, the amines 2,2'-bipyridine, 2,4,6-Iriphenylpyridinine, pyrazine, p