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Selective oxidation of allylic alcohols with chromic acid

✍ Scribed by Harding, Kenn E.; May, Leslie M.; Dick, Kevin F.

Book ID
118028011
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
330 KB
Volume
40
Category
Article
ISSN
0022-3263

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## Abstract The activation parameters for the oxidation of 13 secondary alcohols with chromic acid have been determined. Application of a statistical treatment of __Exner__ [9] shows that the reactions are isoentropic with an average entropy of activation (Ξ”S^β‰ ^) of βˆ’24.0 e. u.

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Strong evidence has accumulated in favor of a conformation for the erythronolide rin& the nucleus of the erythromycin antibiotics, which is approximated by the stereoformula L. '-' This and 2, R,+R,= 0 i.1 R,=OH, R3 =H 5, R,=H, R,=OH closely related3 three-dimensional arrangements lie in a deep well