Chromic acid oxidation of allyl alcohols
β Scribed by Burstein, Sumner H.; Ringold, Howard J.
- Book ID
- 118736438
- Publisher
- American Chemical Society
- Year
- 1967
- Tongue
- English
- Weight
- 506 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
## Abstract The activation parameters for the oxidation of 13 secondary alcohols with chromic acid have been determined. Application of a statistical treatment of __Exner__ [9] shows that the reactions are isoentropic with an average entropy of activation (ΞS^β ^) of β24.0 e. u.
## Abstract The linear free energy relationship of __Sicher__ for relative reactivity towards chromic acid oxidation (ΞΞ__G__) as a function of thermodynamic stability (Ξ__G__) has been reexamined with 23 pairs of epimeric alcohols. The plot of Ξ__G__ __vs__. Ξ__G__ has a slope of 0.8, a correlatio