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Chromic acid oxidation of allyl alcohols

✍ Scribed by Burstein, Sumner H.; Ringold, Howard J.


Book ID
118736438
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
506 KB
Volume
89
Category
Article
ISSN
0002-7863

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## Abstract The activation parameters for the oxidation of 13 secondary alcohols with chromic acid have been determined. Application of a statistical treatment of __Exner__ [9] shows that the reactions are isoentropic with an average entropy of activation (Ξ”S^β‰ ^) of βˆ’24.0 e. u.

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## Abstract The linear free energy relationship of __Sicher__ for relative reactivity towards chromic acid oxidation (ΔΔ__G__) as a function of thermodynamic stability (Ξ”__G__) has been reexamined with 23 pairs of epimeric alcohols. The plot of Ξ”__G__ __vs__. Ξ”__G__ has a slope of 0.8, a correlatio