Selective molecular oxygen oxidation of alkyl sulfides to sulfoxides catalyzed by dichlorotetrakis(dimethyl sulfoxide)ruthenium(II)
โ Scribed by Riley, Dennis P.
- Book ID
- 120597146
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 418 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0020-1669
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๐ SIMILAR VOLUMES
Reactions of Ru"'L(H,O) (L = aminopolycarboxylate ligands viz. edta, pdta, hedtra) with dimethylsulfide (DMS) and dimetbylsulfoxide (DMSO) were studied by using spectrophotomettic, electrochemical and kinetic methods. [RU\*~L(DMS)] complexes formed by the interaction of RumL(H20) and DMS undergo oxi
Under visible light irradiation, the carbonyl ruthenium(II) porphyrin complexes efficiently catalyze the selective oxidation of sulfides to sulfoxides with iodobenzene diacetate [PhI(OAc) 2 ] as the oxygen source. Various thioanisoles and allylic sulfides were oxidized to the corresponding sulfoxide