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Visible light-promoted selective oxidation of sulfides to sulfoxides catalyzed by ruthenium porphyrins with iodobenzene diacetate

✍ Scribed by Chen, Tse-Hong; Yuan, Zhibo; Carver, Aaron; Zhang, Rui

Book ID: 121791069
Publisher: Elsevier Science
Year: 2014
Tongue: English
Weight: 852 KB
Volume: 478
Category: Article
ISSN: 0926-860X
DOI: 10.1016/j.apcata.2014.04.014

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Under visible light irradiation, the carbonyl ruthenium(II) porphyrin complexes efficiently catalyze the selective oxidation of sulfides to sulfoxides with iodobenzene diacetate [PhI(OAc) 2 ] as the oxygen source. Various thioanisoles and allylic sulfides were oxidized to the corresponding sulfoxide

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