Selective hydrogenation of myrcene catalyzed by sol–gel Pd/SiO2
✍ Scribed by Patricia A. Robles-Dutenhefner; Marcelo G. Speziali; Edésia M.B. Sousa; Eduardo N. dos Santos; Elena V. Gusevskaya
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 216 KB
- Volume
- 295
- Category
- Article
- ISSN
- 0926-860X
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📜 SIMILAR VOLUMES
When 1% v/v solution of cinnamaldehyde/toluene was hydrogenated at 25 • C and 47 psi hydrogen pressure over sol-gel Pd/SiO 2 catalysts, a modification effect was observed. Sn and Ir were found to noticeably enhance the selectivity of Pd catalysts with respect to the hydrogenation of the C=O bond rel
diene and 1,7'-octadiene to the corresponding monoenes has been carried out under mild conditions. using different (allyl)Pd(II) den'vatives in NJdimethylacetamide solution. Experiments on the I,3-COD system suggest a mechanism involving the formation of hydrido-Pd(II) species followed by insertion
A series of silica (SiO 2 ) supported iridium catalysts stabilized by cinchona alkaloids was prepared and applied in the heterogeneous asymmetric hydrogenation of acetophenone. Cinchona alkaloids exhibited a marked ability to stabilize and disperse the Ir particles. In the presence of (1S,2S)dipheny