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Selective functionalization of the 1?-position in ferrocenecarbaldehyde

✍ Scribed by Iftime, Gabriel; Moreau-Bossuet, Caroline; Manoury, Eric; Balavoine, Gilbert G. A.


Book ID
121449970
Publisher
Royal Society of Chemistry
Year
1996
Tongue
English
Weight
241 KB
Volume
4
Category
Article
ISSN
1359-7345

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Functionalization reactions of 1-alkynylimidazoles involving the formation of their 2-lithio derivatives followed by addition of various electrophiles are presented. This allows access to previously unreported 1,2-dialkynylimidazoles via 1-alkynyl-2-iodoimidazoles. The use of an aldehyde or sulfonim