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Selective epoxidation of allylic alcohols with dibutyltin oxyperoxide

✍ Scribed by Shigekazu Kanemoto; Tsuyoshi Nonaka; Koichiro Oshima; Kiltiro Utimoto; Hitosi Nozaki

Book ID: 104218883
Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 215 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)84803-0

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✦ Synopsis

Dibutyltin oxyperoxide derived from Bu2SnO and tBuOOH epoxidize allylic alcohols with high stereo-and regioselectivities.

Epoxides are very useful as intermediates in organic synthesis.' Thus,

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