Epoxidation of higher sugar allylic alcohols
✍ Scribed by Sławomir Jarosz
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 575 KB
- Volume
- 183
- Category
- Article
- ISSN
- 0008-6215
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Two series of chiral allylic alcohols, derived from c~,~-unsaturated cyanohydrins, were subjected to asymmetric epoxidation under a variety of conditions. Both achiral (organic peracid, metal-catalyzed peroxide) and chiral (Sharpless titanium-tartrate system) oxidants were applied. Several threo and
4A molecular sieves have shown to be efficient catalysts for regio-and stereoselective epoxidation of allylic alcohols.
The catalytic osmylation of the following higher-carbon sugar allylic alcohols and enones was examined.