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Metallocene-Catalyzed Diastereoselective Epoxidation of Allylic Alcohols

✍ Scribed by Giorgio Della Sala; Lucia Giordano; Alessandra Lattanzi; Antonio Proto; Arrigo Scettri

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 118 KB
Volume: 56
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(00)00266-0

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✦ Synopsis

AbstractÐAllylic alcohols undergo an ef®cient process of diastereoselective epoxidation by t-butyl hydroperoxide (TBHP) in n-hexane solution in the presence of catalytic amounts of mono-and bis-cyclopentadienyl titanium(IV) and zirconium(IV) chlorides.

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