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Selective Conversion of Alcohols into Alkyl Iodides Using a Thioiminium Salt

✍ Scribed by Ellwood, Adam R.; Porter, Michael J.

Book ID
120405701
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
786 KB
Volume
74
Category
Article
ISSN
0022-3263

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✍ Stephen P. Collingwood; Alan P. Davies; Bernard T. Golding πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 225 KB

Treatment of 0-alkylisoureas with trifluoromethanesulphonic acid and a tetrabutylammonium salf (bromide or iodide) affords alkyl halides in high yields. '+?'I 7 f CH,CXCH, b CsH, ,CH(CH,) S CHaCzCCaH, c =-CsH, t h CHaCHgCHCHaCHECHCH, d CsHsCH, i CH3CH&HCH+CCH, e CH,CHECHCH, j CH,=CHCH,C(CH3),CH,