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Selected rate constants for H, O, N, and Cl atoms with substrates at room temperatures

✍ Scribed by J.V. Michael; J.H. Lee


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
501 KB
Volume
51
Category
Article
ISSN
0009-2614

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Rate constants for the reaction of Cl at
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## Abstract Using the standard, low pressure, discharge‐flow technique, with resonance fluorescence in the vacuum ultraviolet to observe Cl atoms, rate constants have been determined for the reaction of Cl atoms with O~3~ at temperatures down to 184 K. The measured rate constants for 298–184 K fit

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The rate constants k,, k2 and t for the reactions of N( 'D) atoms with I-I>, HF, and 02, measured at room temperature in a discharge-flow atomic-resonance-absorption apparatus, have been determined to be (1.8 kO.8) x IO-'\*, (1.0\_+0.3) x lo-'" and (6.6 f 1.0) X lo-l2 cm3 s-l, respectively. Previous

Rate constants for the gas-phase reactio
✍ Ole J. Nielsen; Howard W. Sidebottom; Michael Donlon; Jack Treacy πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 823 KB

## Abstract Rate constants for the reactions of OH radicals and Cl atoms with CH~3~ONO, C~2~H~5~ONO, __n__‐C~3~H~7~ONO, __n__‐C~4~H~9~ONO, and __n__‐C~5~H~11~ONO have been determined at 298 Β± 2 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rat

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Absolute rate constants for the reaction of O(3P) atoms with CHI = CHF, CH2 = CHC1, and CH2 = CHBr have been obtained at 298 f 2Β°K using a modulation phase shift technique. The rate constants ( k z X lo-\* l./mole.sec) obtained are: CH2 = CHF (1.61 =t 0.20), CH2 = CHCl (2.54 + 0.26), and CHZ = CHBr

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✍ Ming-Taun Leu; W.B. Demore πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 516 KB

Constants of the rawions of Cl with HIOz. IX&, 03, CH4, and HNC)J wertt mezxured at 295 K using a flaw discharge-mass spectrometric method. The rate consmts are, WpectiveIy, (6.2 ?c I.51 X 10qzS, (32&) x 10"tl, (1.3 -+. 0.3) X lo-'t, (1.2 ?t 0.3) X 10-13, and (6.8 t 3.4) X lO-is cm3/s.