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Secondary Deuterium Isotope Effects on the Acidity of Carboxylic Acids and Phenols

โœ Scribed by Perrin, Charles L.; Dong, Yanmei


Book ID
120249315
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
99 KB
Volume
129
Category
Article
ISSN
0002-7863

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โœ Prof. Charles L. Perrin; Agnes Flach ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 274 KB

Isotope effects are observed when a reaction rate or equilibrium constant changes as a result of isotopic substitution. [1] They continue to be used as valuable tools to provide insight into molecular structure and reactivity. [2] Secondary isotope effects are those in which the bond to the isotope