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Secondary Deuterium Isotope Effects in the Reactions of Carboxylic Acid Derivatives 1a

โœ Scribed by Bender, Myron L.; Feng, Mary S.

Book ID
121234680
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
548 KB
Volume
82
Category
Article
ISSN
0002-7863

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โœ Stephen Bornemann; Maria-Elena Theoclitou; Martin Brune; Martin R. Webb; Roger N ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 169 KB

Chorismate synthase (EC 4.6.1.4) is the shikimate pathway enzyme that catalyzes the conversion of 5-enolpyruvylshikimate 3-phosphate (EPSP) to chorismate. The enzyme reaction is unusual because it involves a trans-1,4 elimination of the C-3 phosphate and the C-6 proR hydrogen and it has an absolute