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Second-sphere coordination in anion binding: trans-bis­(ethyl­enediamine-κ2N,N′)dinitro­cobalt(III) periodate

✍ Scribed by Sharma, Raj Pal ;Sharma, Rajni ;Bala, Ritu ;Bond, Andrew D.


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
447 KB
Volume
61
Category
Article
ISSN
1600-5368

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Second sphere coordination in anion bind
✍ Rajni Sharma; Raj Pal Sharma; Paula Brandão; Vitor Felix 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 652 KB

Dark maroon coloured single crystals of [cis-Co(en)2(N3)2][trans-Co(NH3)2(NO2)4] were obtained by slowly mixing the separately dissolved [cis-diazidobis(ethylenediamine)cobalt(III)] nitrate with potassium [trans-diamminetetranitrocobaltate(III)] in aqueous medium in 1:1 molar ratio. The complex salt