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Second sphere coordination in anion binding: Synthesis and spectroscopic characterisation of [trans-Co(en)2Cl2]X (X=SCN or N3). Single crystal X-ray structure determination and packing of [trans-Co(en)2Cl2]N3

✍ Scribed by Raj Pal Sharma; Rajni Sharma; Ritu Bala; Paloth Venugopalan


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
268 KB
Volume
787
Category
Article
ISSN
0022-2860

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In an effort to explore [trans-Co(en) 2 Cl 2 ] C as anion receptor for tetrabromocadmate and tetraiodocadmate ion, green coloured single crystals of [trans-Co(en) 2 Cl 2 ]CdBr 4 I and [trans-Co(en) 2 Cl 2 ]CdI 4 II have been obtained by slowly mixing the separately dissolved transdichlorobis(ethylen

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The authors deeply regret that the following error had not been detected before the publishing of the paper. In Table 1, compound 1, the unit cell constants and the cell volume should read: a = 13.3250(4), b = 10.0780(3), c = 13.5170(4), b = 98.888(2), and V = 1793.39(9).