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Second-sphere coordination in anion binding: Synthesis and characterization of hexaamminecobalt(III) salts [Co(NH3)6](L)3·3H2O and [Co(NH3)6]Cl(L)2, L=(CH3)3C6H2SO3 and X-ray structure determination of [Co(NH3)6]Cl(L)2

✍ Scribed by Raj Pal Sharma; Ritu Bala; Rajni Sharma; Kamal Nain Singh; Valeria Ferretti


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
287 KB
Volume
784
Category
Article
ISSN
0022-2860

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Hexaamminecobalt(III) complexes as multi
✍ Ritu Bala; Raj Pal Sharma; Upendra Sharma; Andrew D. Burrows; Kevin Cassar 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 607 KB

The compounds [Co(NH 3 ) 6 ]Br 2 (BF 4 ) 1 and [Co(NH 3 ) 6 ]Cl 2 (HC 2 O 4 )AEH 2 O 2 have been prepared and structurally characterised. The two crystallographically independent cations in 1 are involved in different hydrogen bonding patterns, with one forming predominantly NAHÁ Á ÁF interactions w