Second-sphere coordination complex via hydrogen bonding: synthesis, characterization and X-ray crystal structure of hexaamminecobalt(III)chloride dimethanesulphonate, [Co(NH3)6]Cl(CH3SO3)2
β Scribed by Raj Pal Sharma; Ritu Bala; Rajni Sharma; Paloth Venugopalan
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 207 KB
- Volume
- 694
- Category
- Article
- ISSN
- 0022-2860
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A reddish orange coloured crystalline solid of hexaamminecobalt(III) chloride di(para-nitrobenzoate) was obtained when hexaamminecobalt(III) chloride was reacted with the sodium salt of para-nitrobenzoic acid (1:3 molar ratio) in hot aqueous medium. This cobalt(III) complex salt has been characteriz
The compounds [Co(NH 3 ) 6 ]Br 2 (BF 4 ) 1 and [Co(NH 3 ) 6 ]Cl 2 (HC 2 O 4 )AEH 2 O 2 have been prepared and structurally characterised. The two crystallographically independent cations in 1 are involved in different hydrogen bonding patterns, with one forming predominantly NAHΓ Γ ΓF interactions w