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Second-sphere coordination complex via hydrogen bonding: synthesis, characterization and X-ray crystal structure of hexaamminecobalt(III)chloride dimethanesulphonate, [Co(NH3)6]Cl(CH3SO3)2

✍ Scribed by Raj Pal Sharma; Ritu Bala; Rajni Sharma; Paloth Venugopalan


Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
207 KB
Volume
694
Category
Article
ISSN
0022-2860

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The compounds [Co(NH 3 ) 6 ]Br 2 (BF 4 ) 1 and [Co(NH 3 ) 6 ]Cl 2 (HC 2 O 4 )AEH 2 O 2 have been prepared and structurally characterised. The two crystallographically independent cations in 1 are involved in different hydrogen bonding patterns, with one forming predominantly NAHÁ Á ÁF interactions w