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Second-sphere coordination complexes via hydrogen bonding: Synthesis, characterization of [Co(NH3)6](XO3)3·nH2O (X=Br, I) and single crystal X-ray structure determination of [Co(NH3)6](BrO3)3·0.5H2O

✍ Scribed by Raj Pal Sharma; Ritu Bala; Rajni Sharma; Julio Perez; Daniel Miguel


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
258 KB
Volume
788
Category
Article
ISSN
0022-2860

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✍ Ritu Bala; Raj Pal Sharma; Upendra Sharma; Andrew D. Burrows; Kevin Cassar 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 607 KB

The compounds [Co(NH 3 ) 6 ]Br 2 (BF 4 ) 1 and [Co(NH 3 ) 6 ]Cl 2 (HC 2 O 4 )AEH 2 O 2 have been prepared and structurally characterised. The two crystallographically independent cations in 1 are involved in different hydrogen bonding patterns, with one forming predominantly NAHÁ Á ÁF interactions w