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Scope and Limitations of the Aromatic Anionic [1,3] P–O to P–C Rearrangement in the Synthesis of Chiral o-Hydroxyaryl Diazaphosphonamides

✍ Scribed by Olivier Legrand; Jean Michel Brunel; Gérard Buono


Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
338 KB
Volume
56
Category
Article
ISSN
0040-4020

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📜 SIMILAR VOLUMES


Totally Regio- and Stereoselective P–O-t
✍ Olivier Legrand; Jean Michel Brunel; Gérard Buono 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 323 KB 👁 2 views

The totally regio-and stereoselective P-O-to-P-C exception was found with naphthyl derivatives, which gave mixtures of two regioisomers. In all cases, the products rearrangement in the synthesis of various chiral P-(ohydroxyaryl)diaza-phospholidine P-oxides has been generated have been unambiguously

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The same chemiluminescent spectrum of HNO was obtained in both the reaction systems of 0(3P) + CaHe + NO + 02 (\* A,)/02 and H + NO + 02( 'Ag)/Oa. The reaction mechanism for producing the excited HNO is proposed to be -HNO('A') + 02 ( 'Ag) + HNO(3A", + 0s (3X,) , HNOc3A") + 02 ('A,) --t HNO('A") +