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Totally Stereoselective P–O to P–C Migration Rearrangement: Application to the Synthesis of New Chiral o-Hydroxyaryl Phosphine Oxides

✍ Scribed by Olivier Legrand; Jean Michel Brunel; Thierry Constantieux; Gérard Buono


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
234 KB
Volume
4
Category
Article
ISSN
0947-6539

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Totally Regio- and Stereoselective P–O-t
✍ Olivier Legrand; Jean Michel Brunel; Gérard Buono 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 323 KB 👁 1 views

The totally regio-and stereoselective P-O-to-P-C exception was found with naphthyl derivatives, which gave mixtures of two regioisomers. In all cases, the products rearrangement in the synthesis of various chiral P-(ohydroxyaryl)diaza-phospholidine P-oxides has been generated have been unambiguously