## Abstract Sambucinol (**2**) and sambucoin (**4**), two C~15~‐trichothecenes, have been isolated from cultures of __Fusarium sambucinum__. The structures were deduced from spectroscopic data and by X‐ray diffractoin. A hypothetical biogenetic pathway is proposed.
✦ LIBER ✦
Sambucinic Acid, a New Metabolite of Fusarium sambacinum. 45th communication on verrucarins and roridins
✍ Scribed by Lukas Rösslein; Christoph Tamm; Werner Zücher; Andreas Riesen; Margareta Zehnder
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- German
- Weight
- 294 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
The compound should correctly be named apotrichothec-9-ene-3a, 13-diol, because apotrichothecane is the generic name for the skeleton [4].
We thank Dr. Ruegger, Specfrospin, Fallanden and Prof. H . Fritz, Ciba-Geipy AG, Basel, for recording the spectra and the helpful discussion.
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Ether 8 as well as the subsequent THP ethers are mixtures of diastereoisomers.