Samarium(II) iodide promoted novel reductive coupling reactions of ketones and nitriles
β Scribed by Longhu Zhou; Yongmin Zhang; Daqing Shi
- Book ID
- 108387155
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 209 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Intramolecular Ketone-Nitrile Reductive Coupling Reactions Promoted by Samarium(II) Iodide. -The photochemically induced reaction of keto nitriles of type (I), (III), and (V) with SmI 2 offers an efficient route to prepare monocyclic, fused bicyclic, and bridged Ξ±-hydroxy ketones. 5-exo-Coupling pr
Intramolecular and intermolecular ketone-ester reductive coupling reactions promoted by SmI 2 have been studied. Substituted 2-hydroxy-5-ethoxycarbonylcyclopentanones, 5-ethoxycarbonylcyclopentenones and a-ketols were prepared in moderate to good yields at room temperature or under reflux under neut