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Intramolecular and intermolecular ketone–ester reductive coupling reactions promoted by samarium(II) iodide

✍ Scribed by Yunkui Liu; Yongmin Zhang

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
220 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Intramolecular and intermolecular ketone-ester reductive coupling reactions promoted by SmI 2 have been studied. Substituted 2-hydroxy-5-ethoxycarbonylcyclopentanones, 5-ethoxycarbonylcyclopentenones and a-ketols were prepared in moderate to good yields at room temperature or under reflux under neutral conditions.

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