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Samarium(II) Iodide Promoted Intermolecular Ketone-Olefin Couplings Chelation-Controlled by .alpha.-Hydroxyl Groups

✍ Scribed by Kawatsura, Motoi; Matsuda, Fuyuhiko; Shirahama, Haruhisa


Book ID
127324721
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
271 KB
Volume
59
Category
Article
ISSN
0022-3263

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Intramolecular and intermolecular ketone-ester reductive coupling reactions promoted by SmI 2 have been studied. Substituted 2-hydroxy-5-ethoxycarbonylcyclopentanones, 5-ethoxycarbonylcyclopentenones and a-ketols were prepared in moderate to good yields at room temperature or under reflux under neut