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S-[4-(2,2,4-Trimethyl­chroman-4-yl)phen­yl] N,N-dimethyl­thio­carbamate

✍ Scribed by Lloyd, Gareth O. ;Alen, Jo ;Jacobs, Tia ;Bredenkamp, Martin W. ;Vries, Elise J. C. de


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
434 KB
Volume
62
Category
Article
ISSN
1600-5368

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(S)-O-[4-(2,2,4-Trimethylchroman-4-yl)ph
✍ Jacobs, Tia ;Bredenkamp, Martin W. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 722 KB

Crystallization of the (__S__)-enantiomer of the title compound, C~21~H~26~NO~2~S, from methanol gave an unsolvated crystal structure in which one-dimensional strands of molecules are formed through a series of C—H...O and C—H...S hydrogen bonds, and C—H...π interactions.

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The title compound, [Fe(C 15 H 15 ClNS)(C 14 H 16 N)], crystallizes with the thiocarbamoyl chloride unit nearly coplanar with the cyclopentadienyl ring to which it is attached. There is a slight deviation from planarity which, along with the orientation of the amino substituent on the other cyclopen