Ruthenium(II) Complexes of 2-Aryl-1,10-phenanthrolines: Synthesis, Structure, and Photophysical Properties
✍ Scribed by Wu, Feiyue; Riesgo, Elvira; Pavalova, Anna; Kipp, Rachael A.; Schmehl, Russell H.; Thummel, Randolph P.
- Book ID
- 120998122
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 151 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0020-1669
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## Abstract Friedländer reactions of 4‐aminoacridine‐3‐carbaldehyde with 1,3‐, 1,4‐di‐, and 1,3,5‐triacetylbenzenes afforded a series of corresponding (benzo[b]‐1,10‐phenanthrolin‐2‐yl)benzenes as new N,N,C‐polydentates. Reaction with 1,2‐diacetylbenzene afforded 1,2‐di(benzo[b]‐1,10‐phenanthrol‐2‐
## Abstract The synthesis and the photophysical properties of a series of tetrasubstituted phenanthroline (phen) ruthenium complexes of the type [Ru(tbbpy)~2~(phen‐R~4~)]^2+^ (tbbpy = 4,4′‐di‐__tert__‐butyl‐2,2′‐bipyridine; phen = 1,10‐phenanthroline; R represents the substitution at 3‐, 5‐, 6‐ and