## Abstract Friedländer reactions of 4‐aminoacridine‐3‐carbaldehyde with 1,3‐, 1,4‐di‐, and 1,3,5‐triacetylbenzenes afforded a series of corresponding (benzo[b]‐1,10‐phenanthrolin‐2‐yl)benzenes as new N,N,C‐polydentates. Reaction with 1,2‐diacetylbenzene afforded 1,2‐di(benzo[b]‐1,10‐phenanthrol‐2‐
Synthesis and Photophysical Properties of 3,8-Disubstituted 1,10-Phenanthrolines and Their Ruthenium(II) Complexes
✍ Scribed by Michael Karnahl; Sven Krieck; Helmar Görls; Stefanie Tschierlei; Michael Schmitt; Jürgen Popp; Daniel Chartrand; Garry S. Hanan; Robert Groarke; Johannes G. Vos; Sven Rau
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 362 KB
- Volume
- 2009
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The synthesis and the photophysical properties of a series of tetrasubstituted phenanthroline (phen) ruthenium complexes of the type [Ru(tbbpy)~2~(phen‐R~4~)]^2+^ (tbbpy = 4,4′‐di‐__tert__‐butyl‐2,2′‐bipyridine; phen = 1,10‐phenanthroline; R represents the substitution at 3‐, 5‐, 6‐ and
Highly fluorescent Eu -polymer complexes were synthesized through copolymerization of EuPhen ( Nap ) 2 AA with methyl methacrylate or styrene and their luminescent properties were investigated. The Eu -polymer luminophores showed intense red emission under UV excitation, and the emission intensities