Synthesis, structures, and properties of ruthenium(ii) complexes of N-(1,10-phenanthrolin-2-yl)imidazolylidenes
✍ Scribed by Gu, Shaojin; Liu, Bo; Chen, Jiuxi; Wu, Huayue; Chen, Wanzhi
- Book ID
- 111872777
- Publisher
- Royal Society of Chemistry
- Year
- 2012
- Tongue
- English
- Weight
- 371 KB
- Volume
- 41
- Category
- Article
- ISSN
- 1477-9226
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## Abstract Friedländer reactions of 4‐aminoacridine‐3‐carbaldehyde with 1,3‐, 1,4‐di‐, and 1,3,5‐triacetylbenzenes afforded a series of corresponding (benzo[b]‐1,10‐phenanthrolin‐2‐yl)benzenes as new N,N,C‐polydentates. Reaction with 1,2‐diacetylbenzene afforded 1,2‐di(benzo[b]‐1,10‐phenanthrol‐2‐
## Abstract The synthesis and the photophysical properties of a series of tetrasubstituted phenanthroline (phen) ruthenium complexes of the type [Ru(tbbpy)~2~(phen‐R~4~)]^2+^ (tbbpy = 4,4′‐di‐__tert__‐butyl‐2,2′‐bipyridine; phen = 1,10‐phenanthroline; R represents the substitution at 3‐, 5‐, 6‐ and