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Ruthenium Olefin Metathesis Catalysts for the Ethenolysis of Renewable Feedstocks

✍ Scribed by Yann Schrodi; Thay Ung; Angel Vargas; Garik Mkrtumyan; Choon Woo Lee; Timothy M. Champagne; Richard L. Pederson; Soon Hyeok Hong

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
690 KB
Volume
36
Category
Article
ISSN
1863-0650

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✦ Synopsis

Abstract

Ruthenium olefin metathesis catalysts have been evaluated for the ethenolysis of methyl oleate, a natural seed oil derivative, to produce useful terminal olefins. Several N‐heterocyclic carbene‐based ruthenium catalysts demonstrate good activity and selectivity for the formation of terminal olefins. In particular, catalysts (10) and (21) achieved higher TONs (>20 000).

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