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Integrating the Schrock and Grubbs Catalysts: Ruthenium–Binaphtholate Catalysts for Olefin Metathesis

✍ Scribed by Johanna M. Blacquiere; Robert McDonald; Deryn E. Fogg

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
377 KB
Volume
122
Category
Article
ISSN
0044-8249

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A Novel Class of Ruthenium Catalysts for
A Novel Class of Ruthenium Catalysts for Olefin Metathesis
✍ Thomas Weskamp; Wolfgang C. Schattenmann; Michael Spiegler; Wolfgang A. Herrmann 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 128 KB 👁 2 views

The different nature of carbene ligands is clearly demonstrated by the first ruthenium-based complexes 1, which contain both alkylidene and N-heterocyclic carbene moieties. The latter exhibit a pronounced Lewis base behavior. Moreover, this difference forms the basis of the high catalytic activities