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Ruthenium-Based Four-Coordinate Olefin Metathesis Catalysts

✍ Scribed by Melanie S. Sanford; Lawrence M. Henling; Michael W. Day; Robert H. Grubbs

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
97 KB
Volume
39
Category
Article
ISSN
0044-8249

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Complete experimental details, including synthesis and characterization of all the new compounds, can be found in the Supporting Information.

A Novel Class of Ruthenium Catalysts for
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The different nature of carbene ligands is clearly demonstrated by the first ruthenium-based complexes 1, which contain both alkylidene and N-heterocyclic carbene moieties. The latter exhibit a pronounced Lewis base behavior. Moreover, this difference forms the basis of the high catalytic activities