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Rapidly Initiating Ruthenium Olefin-Metathesis Catalysts

✍ Scribed by Patricio E. Romero; Warren E. Piers; Robert McDonald

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
209 KB
Volume
116
Category
Article
ISSN
0044-8249

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✦ Synopsis

Complete experimental details, including synthesis and characterization of all the new compounds, can be found in the Supporting Information.

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A Novel Class of Ruthenium Catalysts for
A Novel Class of Ruthenium Catalysts for Olefin Metathesis
✍ Thomas Weskamp; Wolfgang C. Schattenmann; Michael Spiegler; Wolfgang A. Herrmann 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 128 KB 👁 2 views

The different nature of carbene ligands is clearly demonstrated by the first ruthenium-based complexes 1, which contain both alkylidene and N-heterocyclic carbene moieties. The latter exhibit a pronounced Lewis base behavior. Moreover, this difference forms the basis of the high catalytic activities