1999 structure structure (organic substances) K 9000 06 -015 A Novel Class of Ruthenium Catalysts for Olefin Metathesis. -Title compounds (I) and (II) are readily prepared by reacting Ph-CH=RuCl 2 (PPh 3 ) 2 or Ph-CH=RuCl 2 (PCy 3 ) 2 with 2.2 equivalents of the appropriate imidazolin-2-ylidene. The
ChemInform Abstract: A Novel Class of Ruthenium Catalysts for Olefin Metathesis
β Scribed by Robert L. Paddock; SonBinh T. Nguyen; Kenneth R. Poeppelmeier
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 24 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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The different nature of carbene ligands is clearly demonstrated by the first ruthenium-based complexes 1, which contain both alkylidene and N-heterocyclic carbene moieties. The latter exhibit a pronounced Lewis base behavior. Moreover, this difference forms the basis of the high catalytic activities
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
## Abstract A novel ruthenium phosphite complex is prepared and efficiently applied as catalyst in ring closing metatheses of alkenes (I), (III), and (V).