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Ruthenium-catalyzed synthesis of 2-ethyl-3-methylquinolines from anilines and triallylamine

✍ Scribed by Chan Sik Cho; Byoung Ho Oh; Sang Chul Shim

Book ID
104260607
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
141 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

Anilines react with triallylamine in dioxane at 180 Β°C in the presence of a catalytic amount of ruthenium chloride and triphenylphosphine together with tin(R) chloride dihydrate to afford the corresponding 2-ethyl-3methylquinolines in good yields.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Ruthenium-Catalyzed
ChemInform Abstract: Ruthenium-Catalyzed Synthesis of 2-Ethyl-3-methylquinolines from Anilines and Triallylamine.
✍ Chan Sik Cho; Byoung Ho Oh; Sang Chul Shim πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 1 views

Ruthenium-Catalyzed Synthesis of 2-Ethyl-3-methylquinolines from Anilines and Triallylamine. -In the presence of catalytic Ru(III), various anilines react with triallylamine and stoichiometric amounts of SnCl 2 to yield 2-ethyl-3-methylquinolines. In the mixtures obtained from m-substituted aniline