ChemInform Abstract: Ruthenium-Catalyzed Synthesis of 2-Ethyl-3-methylquinolines from Anilines and Triallylamine.
β Scribed by Chan Sik Cho; Byoung Ho Oh; Sang Chul Shim
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Ruthenium-Catalyzed Synthesis of 2-Ethyl-3-methylquinolines from Anilines and Triallylamine.
-In the presence of catalytic Ru(III), various anilines react with triallylamine and stoichiometric amounts of SnCl 2 to yield 2-ethyl-3-methylquinolines. In the mixtures obtained from m-substituted anilines [cf. (VI)] formation of the C-7 derivative is favored. o-Toluidine (IX) gives only N-allylamine (X). -(CHO,
π SIMILAR VOLUMES
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