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ChemInform Abstract: Ruthenium-Catalyzed Synthesis of 2-Ethyl-3-methylquinolines from Anilines and Triallylamine.

✍ Scribed by Chan Sik Cho; Byoung Ho Oh; Sang Chul Shim


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Ruthenium-Catalyzed Synthesis of 2-Ethyl-3-methylquinolines from Anilines and Triallylamine.

-In the presence of catalytic Ru(III), various anilines react with triallylamine and stoichiometric amounts of SnCl 2 to yield 2-ethyl-3-methylquinolines. In the mixtures obtained from m-substituted anilines [cf. (VI)] formation of the C-7 derivative is favored. o-Toluidine (IX) gives only N-allylamine (X). -(CHO,


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ChemInform Abstract: Synthesis of Quinol
✍ Chan Sik Cho; Byoung Ho Oh; Sang Chul Shim πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB

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