Ruthenium-Catalyzed Synthesis of 1,2-Diketones from Alkynes
✍ Scribed by Miao, Yanan; Dupé, Antoine; Bruneau, Christian; Fischmeister, Cédric
- Book ID
- 125856022
- Publisher
- John Wiley and Sons
- Year
- 2014
- Tongue
- English
- Weight
- 198 KB
- Volume
- 2014
- Category
- Article
- ISSN
- 1434-193X
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📜 SIMILAR VOLUMES
Regioselective enol ester formation results frcm the addition of saturated and unsaturated carboxylic acids to phenylacetylene in the presence of RuC13, RuClj/2PRj 01 R~C~~(PMe~)(arene~ catalysts. Mononuclear ruthenium complexes, such as RuC13 or RuClz(PR3)(arene), have been shown recently to be mor
A novel 1,3-diene synthetic method from alkyne and ethylene was developed using ruthenium-catalyzed enyne metathesis. The reaction procedure is very simple: A CH2CI 2 solution of alkyne was stirred at room temperature under ethylene gas (1 atm.) in the presence of a catalytic amount of ruthenium ben
The oxidation of organic compounds with a carbon tetrachloride solution of ruthenium tetroxide (RuO4) was first introduced by Djerassi and Engle' in 1953; only recently have the advantages of this powerful oxidizing agent been used in synthesis2.