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Ruthenium Carbene–Diether Ligand Complexes: Catalysts for Hydrogenation of Olefins

✍ Scribed by Wang, Tongen; Pranckevicius, Conor; Lund, Clinton L.; Sgro, Michael J.; Stephan, Douglas W.


Book ID
120065288
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
433 KB
Volume
32
Category
Article
ISSN
0276-7333

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Four ruthenium-N-heterocyclic carbene complexes (3-6) have been prepared and the new compounds characterized by C, H, N analyses, 1 H-NMR and 13 C-NMR. The reduction of ketones to alcohols via transfer hydrogenation was achieved with catalytic amounts of complexes 3-6 in the presence of t-BuOK.