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RuCl2(PPh3)3catalyzed oxidation of secondary alcohols with N-methylmorpholine N-oxide

✍ Scribed by K. Vijayasri; J. Rajaram; J. C. Kuriacose


Book ID
112977178
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1986
Tongue
English
Weight
381 KB
Volume
97
Category
Article
ISSN
0253-4134

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## Abstract The induction period observed in the __cis__‐RuCl~2~(DMSO)~4~ catalyzed oxidation of thioethers (S) to sulfoxides by __N__‐methylmorpholine __N__‐oxide (NMO) is attributed to the rate of formation of the active species viz. RuCl~2~(DMSO)~3~S. Cyclic voltammetric studies indicate formati

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The Ru[lll) Schiff base complex, 1 Ru[ L)CI,ICI; L = Gis[picolinaldehyde) o-phenylenediimine. catalyzes the oxidation of secondary alcohols by N-methylrnorpholine-N-oxide( NMO) or thal-Iium(lll) acetate as oxidant, Kinetic studies showed the formation of R u ( V ) species as the active intermediate