RuCl2(PPh3)3catalyzed oxidation of secondary alcohols with N-methylmorpholine N-oxide
β Scribed by K. Vijayasri; J. Rajaram; J. C. Kuriacose
- Book ID
- 112977178
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 1986
- Tongue
- English
- Weight
- 381 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0253-4134
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π SIMILAR VOLUMES
## Abstract The induction period observed in the __cis__βRuCl~2~(DMSO)~4~ catalyzed oxidation of thioethers (S) to sulfoxides by __N__βmethylmorpholine __N__βoxide (NMO) is attributed to the rate of formation of the active species viz. RuCl~2~(DMSO)~3~S. Cyclic voltammetric studies indicate formati
The Ru[lll) Schiff base complex, 1 Ru[ L)CI,ICI; L = Gis[picolinaldehyde) o-phenylenediimine. catalyzes the oxidation of secondary alcohols by N-methylrnorpholine-N-oxide( NMO) or thal-Iium(lll) acetate as oxidant, Kinetic studies showed the formation of R u ( V ) species as the active intermediate