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Rotationally resolved threshold photoelectron spectroscopy of H2O and H2S

✍ Scribed by Kwanghsi Wang; M.-T. Lee; V. McKoy; Ralph T. Wiedmann; Michael G. White

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 717 KB
Volume: 219
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)00118-9

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✦ Synopsis

We report both measured and calculated rotationally resolved threshold photoelectron spectra for single-photon coherent VUV ionization of the L% 'A, ground state ofjet-cooled HsO and Has. Agreement between the calculated and measured spectra is very encouraging. Both the Hz0 and HsS spectra show type a transitions which arise from odd angular momentum components of the photoelectron matrix element and are quite molecular in origin. These type a transitions, however, are much weaker in HsS due to its more atomiclike character.

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