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Rotational temperature dependence of the branching ratio for the reaction of O+ with HD

โœ Scribed by Viggiano, A. A.; Van Doren, Jane M.; Morris, Robert A.; Williamson, John S.; Mundis, Paul L.; Paulson, John F.; Dateo, Christopher E.

Book ID
120655837
Publisher
American Institute of Physics
Year
1991
Tongue
English
Weight
662 KB
Volume
95
Category
Article
ISSN
0021-9606

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The reaction of O+ with HD has been studied as a function oftranslational energy and hydrogen temperature. While no change in the total cross section as a function of temperature is observed, the branching ratios for formation of OH+ and OD+ do depend upon the HD rotational temperature. The fraction

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## Rate consrants of hydrogen abmaction from CzHsOH by hydroxyl radicals have been measured in the temperature range 300-1000 K by laser-induced fluorescence detection of OH. An Arrhenius evpresslon k(T) = (4.4 f 1.0) x IO-\*\* x exp[(-274 i 90) K/T] cm3/s was derived. Mass spectrometrlc mvestigat