Rotational structure in the infrared spectra of carbon dioxide and nitrous oxide dimers
โ Scribed by R.E. Miller; R.O. Watts
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 458 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
High-resolution infrared predkociation spectra have been measured for dilute mixtures of CO2 and N1O in helium. Rotationalfme structure is clearly resolved for both (C02)2 and (N20)2, the linewidths being instrument-limited. This establishes that predissoaation lirehmes are longer than approGnately 50 ns.
๐ SIMILAR VOLUMES
The structures and the related vibrational spectra of the AICO2 complexes are investigated using a local spin density functional method. The calculations indicate in agreement with a recent spectroscopic study on this system, the existence of two isomers with almost the same energy ( < 2 kcal/mol).
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## Abstract Tobacco and wheat are known to emit nitrous oxide (N~2~O). Provided that N~2~O is a greenhouse gas about 300 times worse than carbon dioxide in its potential for global warming, it is an intriguing and important subject, whether this activity is commonly present in other plants. In this