The self-radiolysis of COZ in excess tritium (3Hz) has been studied at pressures of 0.1 to 1.0 atm, temperatures of -80' to +lOO"C, and in the presence of added HzO, He, or Ar. The primary products of decomposition are C O and 3Hz0. Secondary products are C3H4, CzaH4, and a white polymer. The rates
Radiolysis of acetylene-nitrous oxide mixtures and the effect of carbon dioxide
โ Scribed by K.G. McLaren
- Publisher
- Elsevier Science
- Year
- 1970
- Weight
- 442 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0020-7055
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High-resolution infrared predkociation spectra have been measured for dilute mixtures of CO2 and N1O in helium. Rotationalfme structure is clearly resolved for both (C02)2 and (N20)2, the linewidths being instrument-limited. This establishes that predissoaation lirehmes are longer than approGnately
The self-radiolysis of mixtures of CO and tritium (3H2) has been studied at pressures of 0.25 to 1 .O atmospheres, temperatures of -198" to 4-lOO"C, and in the presence of added HzO or COZ. The products of decomposition are COZ, 3H20, C3H4, G3H4, and a white polymer believed to be polyformaldehyde.